extensions are key values that are part of a certificate.
They are also known as the X509v3 extensions because they are defined in the x509 certificate format.
The most known and extension are:
To know more about the extensions, you can read the section 4.2 of the specification or the openssl documentation
openssl x509 -in cert.pem -noout -text # the whole cert
openssl x509 -in cert.pem -noout -ext subjectAltName,nsCertType # only a subset